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Lemon vs Lime Juice

Similar acidity, different aroma: when a sour wants lemon and when it wants lime.

Which should you use?

Both are sour enough to balance the same measure of syrup, so the choice is about aroma. Lemon is brighter and rounder and sits well with brandy, whisky and gin. Lime is sharper and greener and is the default with rum and tequila. Follow the recipe; it has usually chosen for a reason.

Lemon vs Lime Juice, dimension by dimension
DimensionLemon juiceLime juice
AromaBright, rounded citrusSharp, green, slightly bitter
Classic partnersWhisky, brandy, ginRum, tequila, cachaça
ExamplesWhiskey Sour, Sidecar, Tom CollinsDaiquiri, Margarita, Mojito
After squeezingHolds its character for a few hoursBest used within a few hours

Using one in place of the other

Structurally the swap works — the balance holds — but the drink changes aroma. A Daiquiri with lemon is a recognisably different drink, not a ruined one.